K. S. W. Sing (auth.), Alírio E. Rodrigues, M. Douglas's Adsorption: Science and Technology PDF

By K. S. W. Sing (auth.), Alírio E. Rodrigues, M. Douglas LeVan, Daniel Tondeur (eds.)

ISBN-10: 9400922639

ISBN-13: 9789400922631

ISBN-10: 940107514X

ISBN-13: 9789401075145

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Extra info for Adsorption: Science and Technology

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3 Fit of statistical model (eqn. 30) to experimental isotherm for several systems. ) (10) The isotherms for a number of zeolitic systems have been analyzed in this way and representlO)ve values of the coefficients so derived are summarized in Table 4. 0 Z aZm-xylene) ' CZH6 , CZH4 Molecular interactions insignificant even when 3 molecules in one cage. 0 (n-hep~ane, toiuene, ethylbenzene) No interaction when Z molecules in cage, strong repulsion when 3 molecules in cage. 0 (p-xylene) No interaction when Z molecules in cage, strong attraction when 3 molecules in cage.

Additional support to attend the NATO Adsorption Science and Technology Conference was provided by its Director, Prof. Alirio E. Rodrigues. NOTATION molar area, m 2 /mol A specific surface area, m 2 / g b constant, Eqs. (5), (8) second virial coefficient in gas phase, m S /mol B ts adsorption second virial coefficient, m S /kg C constant, Eqs. (3), (6), (9), (35) D constant, Eq. (4), (15) E exclusion matrix, Eq. (45) ge excess Gibbs free energy In liquid phase, J /mol ge excess free energy in adsorbed phase, J /mol k Boltzmann constant m specific amount adsorbed at saturation, mol/kg n = (N.

E. Jl ll' 121 (1965). F. M. C. Fund. D. F. Choi, Ind. Eng. Chem. , ~, 248 (1978). M. M. Ruthven, Proc. Sixth Internat. Conference on Zeolites, Reno, Nevada 1983, p. 268, A. Bisio and D. , Butterworths, Guildford (1984). INTRODUCTION A solid is commonly called heterogeneous if the adsorption potential is not uniform throughout the surface. The nonuniformity can be caused by several factors such as existence of ions, pore size distribution, and chemisorbed contaminants. Heterogeneity is a system behavior, regardless of the cause of potential variation.

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Adsorption: Science and Technology by K. S. W. Sing (auth.), Alírio E. Rodrigues, M. Douglas LeVan, Daniel Tondeur (eds.)


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