Advanced Materials in Catalysis - download pdf or read online

By Frank Bolz (Auth.)

ISBN-10: 012147450X

ISBN-13: 9780121474508

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Extra resources for Advanced Materials in Catalysis

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And Yates, D . J. C. (1972). / . Catal. 24, 283. , and Boudart, M. (1960). J. Phys. Chem. 64, 204. , and Sachtler, W. M. H. (1967). J. Catal. 7, 300. , and Sachtler, W. M. H. (1968). J. Catal. 12, 35. , Callahan, J. , Millberger, E. C , and Forman, R. W. (1961). Actes Intern. Congr. Catalyse, Paris, 2nd, 1960 2, 2647. Voge, H. , and Adams, C. R. (1967). Adv. Catal. 17, 151. Voge, H. , Wagner, C. D . , and Stevenson, D . P. (1963). J. Catal. 2, 58. Watt, G. , Roper, W. , and Parker, S. G. (1951).

Yakubenok, E. , and Podvyazkin, Yu. A. (1974). Khim. Khim. Tekhnol. Polim. Org. Sint. 73, 29. Yates, D . J. C , and Sinfelt, J. H. (1967). J. Catal. 8, 348. Yates, D . J. C , and Sinfelt, J. H. (1969). J. Catal. 14, 182. 2 Physical and Chemical of Supported Bimetallic Properties Catalysts James J. Burton Robert L. Garten Exxon Research and Engineering Company Linden, New Jersey 1. 11. Introduction 33 T h e C h e m i c a l N a t u r e of B i m e t a l l i c C a t a l y s t s 35 A. Separate Metals or Bimetallic Clusters?

The Mössbauer parameters and dispersions of the bimetallic cata­ lysts given in Fig. 1 are listed in Table I, along with data for bulk P t F e and P d F e alloys. The isomer shift (δ) is the centroid of the Mössbauer spectrum and is determined by the s electron density at the Fe nucleus. Alteration of the nuclear s electron density results primarily from changes in the valence s electrons and the valence d electrons, the latter via changes in the screening of the s electrons. Examination of Table I shows that the isomer shift depends on the nature of the second metal in the bimetallic catalyst.

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Advanced Materials in Catalysis by Frank Bolz (Auth.)


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